Kinetic parameters and nitrate, nitrite changes in bioremediation of Toxic Pentaerythritol Tetranitrate (PETN) contaminated soil

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Kinetic parameters and nitrate, nitrite changes in bioremediation of Toxic Pentaerythritol Tetranitrate (PETN) contaminated soil

Background Cleanup of areas contaminated by explosives is a public health concern. Some explosives can be carcinogenic in humans. Pentaerythritol Tetranitrate (PETN), a powerful explosive with very low water solubility, can be easily transported to ground waters. Objective This study was conducted to determine the removal efficiencies of PETN from soil by bioremediation, and obtain kinetic pa...

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Aerobic degradation of 2,4,6-trinitrotoluene by Enterobacter cloacae PB2 and by pentaerythritol tetranitrate reductase.

Enterobacter cloacae PB2 was originally isolated on the basis of its ability to utilize nitrate esters, such as pentaerythritol tetranitrate (PETN) and glycerol trinitrate, as the sole nitrogen source for growth. The enzyme responsible is an NADPH-dependent reductase designated PETN reductase. E. cloacae PB2 was found to be capable of slow aerobic growth with 2,4,6-trinitrotoluene (TNT) as the ...

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Observations and sources of carbon and nitrogen isotope ratio variation of pentaerythritol tetranitrate (PETN).

Isotope ratio analysis allows forensic investigators to discriminate materials that are chemically identical but differ in their isotope ratios. Here we focused on the discrimination of pentaerythritol tetranitrate (PETN), an explosive with military and civilian applications, using carbon (δ(13)C) and nitrogen (δ(15)N) isotope ratios. Our goal was to understand some of the factors influencing t...

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Explanation of the colossal detonation sensitivity of silicon pentaerythritol tetranitrate (Si-PETN) explosive.

DFT calculations have identified the novel rearrangement shown here for decomposition of the Si derivative of the PETN explosive [PentaErythritol TetraNitrate (PETN), C(CH(2)ONO(2))(4)] that explains the very dramatic increase in sensitivity observed experimentally. The critical difference is that Si-PETN allows a favorable five-coordinate transition state in which the new Si-O and C-O bonds fo...

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Bioremediation of Herbicide-Contaminated Soil and Water

The contamination of soils, groundwater and surface waters by herbicides poses major clean-up problems. At present, the most common approach is containment, involving costly removal of highly contaminated soils to landfill sites. Bioremediation methods for in situ treatment are needed as alternative and/or supplementary approaches for cost-effective and residue-free clean-up. This project focus...

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ژورنال

عنوان ژورنال: Electronic Physician

سال: 2017

ISSN: 2008-5842

DOI: 10.19082/5623